CLBO

CLBO

Supplier
Crylink
Category
Optical Crystals
Origin
China

CLBO (cesium lithium borate, CsLiB₆O₁₀) is a new nonlinear crystal with a broad transparency range (175~2800nm), a high nonlinear coefficient 2.2 times that of KDP, and a small walk-off angle. It has a high laser damage threshold of up to 26GW/cm² and a frequency-doubling conversion efficiency of up to 60% (SHG). It can operate at room temperature and is particularly suitable for producing 4w (266nm) and 5w (213nm) harmonic output from Nd:YAG lasers. It can also be used for ultraviolet parametric generation (OPG) and parametric amplification (OPA).

Specification Snapshot
Crystal Structure
Tetragonal negative uniaxial crystal, 42 m
Damage Threshold
26 GW/cm²
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Overview

CLBO (cesium lithium borate, CsLiB₆O₁₀) is a new nonlinear crystal with a broad transparency range (175~2800nm), a high nonlinear coefficient 2.2 times that of KDP, and a small walk-off angle. It has a high laser damage threshold of up to 26GW/cm² and a frequency-doubling conversion efficiency of up to 60% (SHG). It can operate at room temperature and is particularly suitable for producing 4w (266nm) and 5w (213nm) harmonic output from Nd:YAG lasers. It can also be used for ultraviolet parametric generation (OPG) and parametric amplification (OPA).

Specifications

ParameterValue
Chemical formulaCsLiB₆O₁₀
Crystal StructureTetragonal negative uniaxial crystal, 42 m
Lattice constanta=10.494Å,c = 8.939Å,Z=4
Mass density2.461 g/cm³
Mohs hardness5.5
Melting point1118 K
Molecular mass364.706
Thermal conductivity1.25 W/m K
NLO coefficientdₑff(I)=d₃₆sinθmsin(2φ)
NLO coefficientdₑff(II)=d₃₆sin(2θm)cos(2φ)
Thermo-optic coefficient dnₒ/dTdnₒ/dT=-1.9*10⁻⁶/℃
Thermo-optic coefficient dnₑ/dTdnₑ/dT=-0.5*10⁻⁶/℃
Damage Threshold26 GW/cm²
Wavelength532 + 532 = 266
Wavelength1064 + 266 = 213
Phase-matching angle61.7 °
Phase-matching angle68.4 °
Flow rate0.84 pm / V
Flow rate0.87 pm / V
Angle Tolerance0.49 mrad·cm
Angle Tolerance0.42 mrad·cm
Deviation angle1.83 °
Deviation angle1.69 °
Spectral acceptance0.13 nm·cm
Spectral acceptance0.16 nm·cm
Temperature acceptance8.3 ℃·cm
Temperature acceptance4.6 ℃·cm
Transparency range180-2750 nm
Absorption coefficient0.0013 cm−¹
Refractive index [1.064 μm]nₑ = 1.4340, nₒ = 1.4838
Refractive index [0.532 μm]nₑ = 1.4445, nₒ = 1.4971
Sellmeier equation (λ in μmnₒ² = 2.2104+0.01018/(λ²-0.01424)-0.01258λ²
Sellmeier equation (λ in μmnₑ² = 2.0588+0.00838/(λ²-0.01363)-0.00607λ²
Refractive index nₒ [λ[µm]:0.42 / nₑ:1.4517]1.5058
Refractive index nₑ [λ[µm]:0.42 / nₒ:1.5058]1.4517
Refractive index nₒ [λ[µm]:0.45 / nₑ:1.4493]1.503
Refractive index nₑ [λ[µm]:0.45 / nₒ:1.503]1.4493
Refractive index nₒ [λ[µm]:0.48 / nₑ:1.4474]1.5006
Refractive index nₑ [λ[µm]:0.48 / nₒ:1.5006]1.4474
Refractive index nₒ [λ[µm]:0.5 / nₑ:1.4462]1.4991
Refractive index nₑ [λ[µm]:0.5 / nₒ:1.4991]1.4462
Refractive index nₒ [λ[µm]:0.532 / nₑ:1.4445]1.4971
Refractive index nₑ [λ[µm]:0.532 / nₒ:1.4971]1.4445
Refractive index nₒ [λ[µm]:0.56 / nₑ:1.4434]1.4957
Refractive index nₑ [λ[µm]:0.56 / nₒ:1.4957]1.4434
Refractive index nₒ [λ[µm]:0.59 / nₑ:1.4422]1.4943
Refractive index nₑ [λ[µm]:0.59 / nₒ:1.4943]1.4422
Refractive index nₒ [λ[µm]:0.61 / nₑ:1.4414]1.4935
Refractive index nₑ [λ[µm]:0.61 / nₒ:1.4935]1.4414
Refractive index nₒ [λ[µm]:0.6328 / nₑ:1.4409]1.4928
Refractive index nₑ [λ[µm]:0.6328 / nₒ:1.4928]1.4409
Refractive index nₒ [λ[µm]:0.67 / nₑ:1.4398]1.4915
Refractive index nₑ [λ[µm]:0.67 / nₒ:1.4915]1.4398
Refractive index nₒ [λ[µm]:0.7 / nₑ:1.4392]1.4907
Refractive index nₑ [λ[µm]:0.7 / nₒ:1.4907]1.4392
Refractive index nₒ [λ[µm]:0.72 / nₑ:1.4387]1.4902
Refractive index nₑ [λ[µm]:0.72 / nₒ:1.4902]1.4387
Refractive index nₒ [λ[µm]:1.064 / nₑ:1.434]1.4838
Refractive index nₑ [λ[µm]:1.064 / nₒ:1.4838]1.434
Phase-matching temperature, internal angle and temperature bandwidth - θₚₘ [SHG, o + o ⇒ e / Interaction wavelengths [μm]:0.946 ⇒ 0.473 / T [◦C]:-15 / ΔT [◦C]:5]90 deg
Phase-matching temperature, internal angle and temperature bandwidth - T [SHG, o + o ⇒ e / Interaction wavelengths [μm]:0.946 ⇒ 0.473 / θₚₘ [deg]:90 / ΔT [◦C]:5]-15 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - ΔT [SHG, o + o ⇒ e / Interaction wavelengths [μm]:0.946 ⇒ 0.473 / θₚₘ [deg]:90 / T [◦C]:-15]5 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - θₚₘ [SHG, o + o ⇒ e / Interaction wavelengths [μm]:0.5235 ⇒ 0.26175 / T [◦C]:~160]65.8 deg
Phase-matching temperature, internal angle and temperature bandwidth - T [SHG, o + o ⇒ e / Interaction wavelengths [μm]:0.5235 ⇒ 0.26175 / θₚₘ [deg]:65.8]~160 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - θₚₘ [SHG, o + o ⇒ e / Interaction wavelengths [μm]:0.5321 ⇒ 0.26605 / T [◦C]:~140]62 deg
Phase-matching temperature, internal angle and temperature bandwidth - T [SHG, o + o ⇒ e / Interaction wavelengths [μm]:0.5321 ⇒ 0.26605 / θₚₘ [deg]:62]~140 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - θₚₘ [SHG, o + o ⇒ e / T [◦C]:20 / Δθⁱⁿt [deg]:0.23 / ΔT [◦C]:6.2]61.4 deg
Phase-matching temperature, internal angle and temperature bandwidth - T [SHG, o + o ⇒ e / θₚₘ [deg]:61.4 / Δθⁱⁿt [deg]:0.23 / ΔT [◦C]:6.2]20 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - Δθⁱⁿt [SHG, o + o ⇒ e / θₚₘ [deg]:61.4 / T [◦C]:20 / ΔT [◦C]:6.2]0.23 deg
Phase-matching temperature, internal angle and temperature bandwidth - ΔT [SHG, o + o ⇒ e / θₚₘ [deg]:61.4 / T [◦C]:20 / Δθⁱⁿt [deg]:0.23]6.2 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - θₚₘ [SHG, o + o ⇒ e / Interaction wavelengths [μm]:1.0642 ⇒ 0.5321 / T [◦C]:20 / Δθⁱⁿt [deg]:0.043 / ΔT [◦C]:52.7]29.5 deg
Phase-matching temperature, internal angle and temperature bandwidth - T [SHG, o + o ⇒ e / Interaction wavelengths [μm]:1.0642 ⇒ 0.5321 / θₚₘ [deg]:29.5 / Δθⁱⁿt [deg]:0.043 / ΔT [◦C]:52.7]20 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - Δθⁱⁿt [SHG, o + o ⇒ e / Interaction wavelengths [μm]:1.0642 ⇒ 0.5321 / θₚₘ [deg]:29.5 / T [◦C]:20 / ΔT [◦C]:52.7]0.043 deg
Phase-matching temperature, internal angle and temperature bandwidth - ΔT [SHG, o + o ⇒ e / Interaction wavelengths [μm]:1.0642 ⇒ 0.5321 / θₚₘ [deg]:29.5 / T [◦C]:20 / Δθⁱⁿt [deg]:0.043]52.7 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - θₚₘ [SHG, o + o ⇒ e / Interaction wavelengths [μm]:1.3382 ⇒ 0.6691 / T [◦C]:20 / ΔT [◦C]:68.7]27.7 deg
Phase-matching temperature, internal angle and temperature bandwidth - T [SHG, o + o ⇒ e / Interaction wavelengths [μm]:1.3382 ⇒ 0.6691 / θₚₘ [deg]:27.7 / ΔT [◦C]:68.7]20 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - ΔT [SHG, o + o ⇒ e / Interaction wavelengths [μm]:1.3382 ⇒ 0.6691 / θₚₘ [deg]:27.7 / T [◦C]:20]68.7 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - θₚₘ [SFG, o + o ⇒ e / Interaction wavelengths [μm]:1.0642 + 0.26605 ⇒ 0.21284 / T [◦C]:20 / ΔT [◦C]:3.6]67.3 deg
Phase-matching temperature, internal angle and temperature bandwidth - T [SFG, o + o ⇒ e / Interaction wavelengths [μm]:1.0642 + 0.26605 ⇒ 0.21284 / θₚₘ [deg]:67.3 / ΔT [◦C]:3.6]20 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - ΔT [SFG, o + o ⇒ e / Interaction wavelengths [μm]:1.0642 + 0.26605 ⇒ 0.21284 / θₚₘ [deg]:67.3 / T [◦C]:20]3.6 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - θₚₘ [SFG, o + o ⇒ e / Interaction wavelengths [μm]:1.547 + 0.221 ⇒ 0.19338 / T [◦C]:150]61.7 deg
Phase-matching temperature, internal angle and temperature bandwidth - T [SFG, o + o ⇒ e / Interaction wavelengths [μm]:1.547 + 0.221 ⇒ 0.19338 / θₚₘ [deg]:61.7]150 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - θₚₘ [SFG, o + o ⇒ e / Interaction wavelengths [μm]:1.9079 + 0.2128 ⇒ 0.1914 / T [◦C]:20 / ΔT [◦C]:1.2]55 deg
Phase-matching temperature, internal angle and temperature bandwidth - T [SFG, o + o ⇒ e / Interaction wavelengths [μm]:1.9079 + 0.2128 ⇒ 0.1914 / θₚₘ [deg]:55 / ΔT [◦C]:1.2]20 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - ΔT [SFG, o + o ⇒ e / Interaction wavelengths [μm]:1.9079 + 0.2128 ⇒ 0.1914 / θₚₘ [deg]:55 / T [◦C]:20]1.2 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - θₚₘ [SFG, o + o ⇒ e / Interaction wavelengths [μm]:1.0642 + 0.35473 ⇒ 0.26605 / T [◦C]:20 / ΔT [◦C]:6.1]50.6 deg
Phase-matching temperature, internal angle and temperature bandwidth - T [SFG, o + o ⇒ e / Interaction wavelengths [μm]:1.0642 + 0.35473 ⇒ 0.26605 / θₚₘ [deg]:50.6 / ΔT [◦C]:6.1]20 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - ΔT [SFG, o + o ⇒ e / Interaction wavelengths [μm]:1.0642 + 0.35473 ⇒ 0.26605 / θₚₘ [deg]:50.6 / T [◦C]:20]6.1 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - θₚₘ [SFG, o + o ⇒ e / Interaction wavelengths [μm]:1.0642 + 0.5321 ⇒ 0.35473 / T [◦C]:20 / ΔT [◦C]:18]39.1 deg
Phase-matching temperature, internal angle and temperature bandwidth - T [SFG, o + o ⇒ e / Interaction wavelengths [μm]:1.0642 + 0.5321 ⇒ 0.35473 / θₚₘ [deg]:39.1 / ΔT [◦C]:18]20 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - ΔT [SFG, o + o ⇒ e / Interaction wavelengths [μm]:1.0642 + 0.5321 ⇒ 0.35473 / θₚₘ [deg]:39.1 / T [◦C]:20]18 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - θₚₘ [SHG, e + o ⇒ e / Interaction wavelengths [μm]:1.0642 ⇒ 0.5321 / T [◦C]:20 / ΔT [◦C]:49.4]42.4 deg
Phase-matching temperature, internal angle and temperature bandwidth - T [SHG, e + o ⇒ e / Interaction wavelengths [μm]:1.0642 ⇒ 0.5321 / θₚₘ [deg]:42.4 / ΔT [◦C]:49.4]20 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - ΔT [SHG, e + o ⇒ e / Interaction wavelengths [μm]:1.0642 ⇒ 0.5321 / θₚₘ [deg]:42.4 / T [◦C]:20]49.4 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - θₚₘ [SFG, e + o ⇒ e / Interaction wavelengths [μm]:1.9079 + 0.2128 ⇒ 0.1914 / T [◦C]:20 / ΔT [◦C]:1.1]57.4 deg
Phase-matching temperature, internal angle and temperature bandwidth - T [SFG, e + o ⇒ e / Interaction wavelengths [μm]:1.9079 + 0.2128 ⇒ 0.1914 / θₚₘ [deg]:57.4 / ΔT [◦C]:1.1]20 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - ΔT [SFG, e + o ⇒ e / Interaction wavelengths [μm]:1.9079 + 0.2128 ⇒ 0.1914 / θₚₘ [deg]:57.4 / T [◦C]:20]1.1 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - θₚₘ [SFG, e + o ⇒ e / Interaction wavelengths [μm]:1.0642 + 0.5321 ⇒ 0.35473 / T [◦C]:20 / ΔT [◦C]:17]48.9 deg
Phase-matching temperature, internal angle and temperature bandwidth - T [SFG, e + o ⇒ e / Interaction wavelengths [μm]:1.0642 + 0.5321 ⇒ 0.35473 / θₚₘ [deg]:48.9 / ΔT [◦C]:17]20 ◦C
Phase-matching temperature, internal angle and temperature bandwidth - ΔT [SFG, e + o ⇒ e / Interaction wavelengths [μm]:1.0642 + 0.5321 ⇒ 0.35473 / θₚₘ [deg]:48.9 / T [◦C]:20]17 ◦C

Key Features

Small walk-off angle; low absorption coefficient; high frequency-conversion efficiency; single crystals that are easy to grow; high laser damage threshold; effective nonlinear optical coefficient; an ultraviolet absorption edge reaching 180 nm; large angular, spectral and temperature bandwidths.

Datasheet

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Supplier Information

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Crylink
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Shanghai Crylink Technology Co., Ltd. was jointly established by Shanghai Yangtze Delta Innovation Institute, Baoshan District state-owned platform, and Dr. Yongjun Dong's team. Located in Baoshan High-tech Industrial Park, the company focuses on R&D and production of laser materials and devices. Main products include laser crystals, nonlinear crystals, bonded crystals, and devices, with full-chain capabilities from crystal growth, optical polishing, laser coating to device packaging. Its subsidiary, Nanjing Guangbao Optoelectronics Technology Co., Ltd., operates the 'Meta-laser' and 'Guangbao Optoelectronics' brands. Products are widely used in laser processing, medical aesthetics, LiDAR, optical communications, defense, scientific research, aerospace, and other fields.

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