LiInSe₂ — Lithium Indium Selenide

LiInSe₂ — Lithium Indium Selenide

Supplier
Thz-chip
Category
Optical Crystals
Origin
China

Lithium indium diselenide (LiInSe₂, LISe) is a new biaxial nonlinear-optical crystal in the orthorhombic system, point group mm2. Directional solidification or vertical Bridgman growth typically yields dark-red crystals about 20mm long and 10mm in diameter. Broad 0.43–13.2μm transmission, a large nonlinear coefficient and high damage threshold make it an excellent mid-IR nonlinear crystal. Containing the 6Li isotope, it also combines semiconductor/scintillator properties for room-temperature thermal-neutron detection.

Specification Snapshot
Crystal Structure
Typ: Orthorhombic Crystal System, Point Group mm2, Space Group Pna21
Transmission Range
typical:0.43~13.2μm
Refractive Index [@10μm]
Typ: nx=2.2015,ny=2.2522,nz=2.2566
Laser Damage Threshold [1064nm; 10ns Pulses]
typical:~40GW/cm² (1064nm, 10ns Pulses)
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Overview

Lithium indium diselenide (LiInSe₂, LISe) is a new biaxial nonlinear-optical crystal in the orthorhombic system, point group mm2. Directional solidification or vertical Bridgman growth typically yields dark-red crystals about 20mm long and 10mm in diameter. Broad 0.43–13.2μm transmission, a large nonlinear coefficient and high damage threshold make it an excellent mid-IR nonlinear crystal. Containing the 6Li isotope, it also combines semiconductor/scintillator properties for room-temperature thermal-neutron detection.

Specifications

ParameterValue
Crystal StructureTyp: Orthorhombic Crystal System, Point Group mm2, Space Group Pna21
Unit-Cell Parameterstypical:a=7.192~7.218Å,b=8.412~8.441Å,c=6.772~6.793Å
Melting Pointtypical:904°C
Transmission Rangetypical:0.43~13.2μm
Nonlinear Coefficient [@2.3μm]typical:d₃₁=11.78pm/V,d₂₄=8.17pm/V(@2.3μm)
Room-Temperature Bandgap [Room Temperature]typical:1.88~2.86eV
Room-Temperature Resistivity [Room Temperature; n-Type]typical:~1×10¹⁰-1×10¹¹Ω cm (n-Type)
Refractive Index [@10μm]Typ: nx=2.2015,ny=2.2522,nz=2.2566
Laser Damage Threshold [1064nm; 10ns Pulses]typical:~40GW/cm² (1064nm, 10ns Pulses)
Thermal Conductivitytypical:kx=4.73,ky=4.67,kz=5.45W/(m K)

Applications

Mid-IR Generation:LiInSe₂ Is a Core Nonlinear Frequency-Conversion Crystal;OPO/OPA/DFG Give Tunable Output in Source Band“312μm”;Reported Tunable Bands“3.54.8μm”and7–12μm;Military/Defense:IR Guidance,Warning,Countermeasures,Communications;Civil Sensing:Trace Gas,IR Spectroscopy,Industrial Process Inspection,Oil Extraction,Drug Detection,Also Medical IR Laser Diagnosis/Treatment;Thermal Neutrons:6Li Has Very Large Capture Cross Section,LiInSe₂ Is a New Room-Temperature Semiconductor Thermal-Neutron Detector Material,95%6Li Enrichment Enables High Efficiency;Both Semiconductor/Scintillator Properties for Low-Noise Room-Temperature Operation;Research:Nonlinear Optics,Mid-IR Laser Physics,Spectral Analysis

Datasheet

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Supplier Information

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Thz-chip
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Xi'an Taihe Dixin Technology Co., Ltd. is a technology enterprise established through the transformation of achievements from the State Key Laboratory of Solidification Processing and the Key Laboratory of Radiation Detection Materials and Devices of the Ministry of Industry and Information Technology at Northwestern Polytechnical University. The company focuses on the growth of electro-optic crystals for terahertz (THz) wave generation and detection, high-energy ray and particle detection semiconductor crystals, and the design, preparation, and production of related devices, mastering core preparation technologies for advanced semiconductor crystal materials. Currently, it can produce large-size high-quality ZnTe crystals, organic semiconductor crystals BNA, perovskite crystals CsPbBr₃, neutron detection crystals 6LiInSe2, etc., and provide devices, systems, and testing solutions, offering a full-chain service of 'special functional crystals + core devices + intelligent equipment + solutions', empowering the high-quality development of industries such as aviation, aerospace, and nuclear energy.

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LiInSe₂ — Lithium Indium Selenide
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