KTP Electro-optic crystal

KTP Electro-optic crystal

Supplier
Crylink
Category
Optical Crystals
Origin
China

KTP, or potassium titanyl phosphate, offers excellent nonlinear and electro-optic properties. Its high electro-optic coefficient and low dielectric constant support high-frequency operation and electro-optic Q-switching. It also offers strong frequency-doubling performance, with a large nonlinear coefficient, no walk-off, a high optical-damage threshold and little temperature dependence of phase matching. It is used for 1064-532nm frequency doubling in medium- and low-power Nd:YAG and Nd:YVO₄ lasers. High nonlinearity, mechanical stability, optical quality and transparency from 350 nm–4500nm support its broad use as a nonlinear medium. It is particularly useful for intracavity and extracavity frequency doubling of medium- and low-power neodymium lasers. Applications also include SHG for green/red output from Nd-doped lasers and sum-frequency mixing (SFM) for blue output from Nd lasers and diode lasers.

Specification Snapshot
Material
KTiOPO₄
Surface Quality
10/5 S/D
Crystal Structure
Orthorhombic point group: mm²
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Overview

KTP, or potassium titanyl phosphate, offers excellent nonlinear and electro-optic properties. Its high electro-optic coefficient and low dielectric constant support high-frequency operation and electro-optic Q-switching. It also offers strong frequency-doubling performance, with a large nonlinear coefficient, no walk-off, a high optical-damage threshold and little temperature dependence of phase matching. It is used for 1064-532nm frequency doubling in medium- and low-power Nd:YAG and Nd:YVO₄ lasers. High nonlinearity, mechanical stability, optical quality and transparency from 350 nm–4500nm support its broad use as a nonlinear medium. It is particularly useful for intracavity and extracavity frequency doubling of medium- and low-power neodymium lasers. Applications also include SHG for green/red output from Nd-doped lasers and sum-frequency mixing (SFM) for blue output from Nd lasers and diode lasers.

Specifications

ParameterValue
MaterialKTiOPO₄
Cut-angle orientation accuracy<30 arcmin
Phase matchingType Ⅱ, θ=90°; φ=phase-matching angle
Phase-matching range497-3300nm
Angle ToleranceΔθ≤0.25°,ΔΦ≤0.25°
Dimensional tolerance(width ±0.1mm) × (height ±0.1mm) × (length +0.5/-0.1mm), length ≥2.5mm
Dimensional tolerance(width ±0.1mm) × (height ±0.1mm) × (length +0.1/-0.1mm), length <2.5mm
Flatness [@633nm]<λ/8 @633nm
Surface Quality10/5 S/D
Parallelism<10 arcsec
Perpendicularity≤5 arcmin
Coating [@1064nm R<0.1%]a) S1&S2:AR@1064nm R<0.1%
Coating [@532nm, R<0.25%]AR@532nm, R<0.25%
Coating [@1064nm,R>99.8%]b) S1:HR@1064nm,R>99.8%
Coating [@808nm,T>5%]High temperature @808nm,T>5%
Coating [@1064nm, R<0.1%]S2: HR@1064nm, R<0.1%
CoatingCoatings can be customized to user requirements
Crystal StructureOrthorhombic point group: mm²
Lattice parametersa=6.404Å,b=10.615Å,c=12.814Å,z=8
Melting point~1172℃
Transition temperature936℃
Decomposition temperature~1150℃
Optical homogeneitydn~10⁻⁶/cm
Hardness~5
Density3.01g/cm³
Specific heat0.1737cal/g.℃
Absorption coefficient [@1064nm and 532nm]a<1%/cm@1064nm and 532nm
HygroscopicityNo
Dielectric constant13
Coefficient of thermal expansion [In the range 25℃-900℃]a1=11×10⁻⁶ ℃⁻¹
Coefficient of thermal expansion [In the range 25℃-900℃]a2=9×10⁻⁶℃⁻¹
Coefficient of thermal expansion [In the range 25℃-900℃]a3=0.6×10⁻⁶ ℃⁻¹
Thermal conductivityk1=2.0×10⁻² W/cm ℃
Thermal conductivityk2=3.0×10 ⁻²W/cm ℃
Thermal conductivityk3=3.3×10⁻² W/cm ℃
Electrical conductivity3.5×10⁻⁸ s/cm (c axis, 22℃, 1kHz)
Transparency range497-1800nm
Thermo-optic coefficient dnₓ/dTdnₓ/dT=1.1×10⁻⁵/℃
Thermo-optic coefficient dn_y/dTdn_y/dT=1.3×10⁻⁵/℃
Thermo-optic coefficient dn_z/dTdn_z/dT=1.6×10⁻⁵/℃
Sellmeier equationnₓ²=3.0065+0.03901/(I2-0.04251)-0.01327I2
Sellmeier equationn_y²=3.0333+0.04154/(I2-0.04527)-0.01408I2
Sellmeier equationn_z²=3.3134+0.05694/(I2-0.05658)-0.01682I2
Effective nonlinear optical coefficientdeff(Ⅱ)≈(d₂₄-d₁₅)sin2θsin2φ-(d₁₅sin2φ+d₂₄cos2φ)sinθ
Damage Threshold [@1064nm]>0.5GW/cm³ for 10ns pulses @1064nm

Key Features

High damage threshold; high-temperature stability; low half-wave voltage; readily grown into large crystals; large acceptance angle and small walk-off angle; broad temperature and spectral ranges; high photoelectric coefficient and low dielectric constant; non-water-absorbing, with stable chemical and mechanical properties.

Datasheet

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Supplier Information

Cr
Crylink
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Shanghai Crylink Technology Co., Ltd. was jointly established by Shanghai Yangtze Delta Innovation Institute, Baoshan District state-owned platform, and Dr. Yongjun Dong's team. Located in Baoshan High-tech Industrial Park, the company focuses on R&D and production of laser materials and devices. Main products include laser crystals, nonlinear crystals, bonded crystals, and devices, with full-chain capabilities from crystal growth, optical polishing, laser coating to device packaging. Its subsidiary, Nanjing Guangbao Optoelectronics Technology Co., Ltd., operates the 'Meta-laser' and 'Guangbao Optoelectronics' brands. Products are widely used in laser processing, medical aesthetics, LiDAR, optical communications, defense, scientific research, aerospace, and other fields.

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