MgO:LiNbO₃

MgO:LiNbO₃

Supplier
Crylink
Category
Optical Crystals
Origin
China

Compared with undoped LiNbO₃, MgO-doped LiNbO₃ crystals have a higher optical damage threshold and nonlinear conversion efficiency. Doping also increases the Raman scattering cross section and reduces phonon-mode loss. MgO:LiNbO₃ has distinctive advantages over LiNbO₃ in NCPM frequency doubling, frequency mixing, and optical parametric oscillation with Nd-doped lasers. Frequency-doubling efficiencies exceeding 65% and 45% can be obtained with pulsed and continuous-wave Nd:YAG lasers, respectively. MgO:LiNbO₃ is widely used in optical parametric oscillation (OPO), optical parametric amplification (OPA), quasi-phase matching, and integrated optical waveguides.

Specification Snapshot
Refractive Index [Magnesium-doped lithium niobate / 25°C / 355nm]
2.38482
Refractive Index [Magnesium-doped lithium niobate / 25°C / 406nm]
2.31248
Refractive Index [Magnesium-doped lithium niobate / 25°C / 532nm]
2.2253
Refractive Index [Magnesium-doped lithium niobate / 25°C / 633nm]
2.19323
Refractive Index [Magnesium-doped lithium niobate / 25°C / 1064nm]
2.14757
Refractive Index [Magnesium-doped lithium niobate / 50°C / 355nm]
2.38778
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Overview

Compared with undoped LiNbO₃, MgO-doped LiNbO₃ crystals have a higher optical damage threshold and nonlinear conversion efficiency. Doping also increases the Raman scattering cross section and reduces phonon-mode loss. MgO:LiNbO₃ has distinctive advantages over LiNbO₃ in NCPM frequency doubling, frequency mixing, and optical parametric oscillation with Nd-doped lasers. Frequency-doubling efficiencies exceeding 65% and 45% can be obtained with pulsed and continuous-wave Nd:YAG lasers, respectively. MgO:LiNbO₃ is widely used in optical parametric oscillation (OPO), optical parametric amplification (OPA), quasi-phase matching, and integrated optical waveguides.

Specifications

ParameterValue
Phase-matching angle - Φₑₓₚ [SHG, o+o ⇒ e / Interaction wavelength[μm]:1.0642⇒0.5321 / Note:5mol% MgO, all LN]74.5 deg
Phase-matching angle - Φₑₓₚ [SHG, o+o ⇒ e / Interaction wavelengths [μm]:1.0642⇒0.5321 / Note:5mol% MgO]76 deg
Phase-matching angle - Φₑₓₚ [SHG, o+o ⇒ e / Interaction wavelengths [μm]:1.0642⇒0.5321 / Note:5mol% MgO, Li/Nb=0.97]76.5 deg
Phase-matching angle - Φₑₓₚ [SHG, o+o ⇒ e / Interaction wavelengths [μm]:1.0642⇒0.5321 / Note:7mol% MgO]82.3 deg
Phase-matching angle - Φₑₓₚ [SHG, o+o ⇒ e / Interaction wavelength[μm]:1.0795⇒0.53975 / Note:5mol% MgO, all LN]75.1 deg
Phase-matching angle - Φₑₓₚ [SHG, o+o ⇒ e / Interaction wavelengths [μm]:1.0796⇒0.5398 / Note:5mol% MgO, Li/Nb=0.97]74 deg
Phase-matching angle - Φₑₓₚ [SHG, o+o ⇒ e / Interaction wavelength[μm]:1.3414⇒0.6707 / Note:5mol% MgO, all LN]54 deg
NCPM Temperature -T [SHG, o+o ⇒ e / Interaction wavelengths [μm]:1.047⇒0.5235]75.3 ℃
NCPM Temperature -T [SHG, o+o ⇒ e / Interaction wavelength[μm]:1.0642⇒0.5321 / Note:0.6mol% MgO, all LN]25.4 ℃
NCPM Temperature -T [SHG, o+o ⇒ e / Interaction wavelength[μm]:1.0642⇒0.5321 / Note:7mol% MgO, along X]78.5 ℃
NCPM Temperature -T [SHG, o+o ⇒ e / Interaction wavelength[μm]:1.0642⇒0.5321 / Note:>5mol% MgO]85–109 ℃
NCPM Temperature -T [SHG, o+o ⇒ e / Interaction wavelength[μm]:1.0642⇒0.5321 / Note:5mol% MgO]107 ℃
NCPM Temperature -T [SHG, o+o ⇒ e / Interaction wavelength[μm]:1.0642⇒0.5321 / Note:5mol% MgO]110 ℃
NCPM Temperature -T [SHG, o+o ⇒ e / Interaction wavelength[μm]:1.0642⇒0.5321 / Note:5mol% MgO]110.6 ℃
NCPM Temperature -T [SHG, o+o ⇒ e / Interaction wavelength[μm]:1.0642⇒0.5321 / Note:7mol% MgO]110.8 ℃
NCPM Temperature -T [SHG, o+o ⇒ e / Interaction wavelength[μm]:1.0795⇒0.53975 / Note:5mol% MgO, all LN]115 ℃
Angular and temperature bandwidth - T [SHG, o+o ⇒ e / Interaction wavelengths [μm]:1.0642⇒0.5321 / θₚₘ[deg]:76 / Δθⁱⁿt[deg]:0.063 / Note:5mol% MgO]20 ℃
Angular and temperature bandwidth - θₚₘ [SHG, o+o ⇒ e / Interaction wavelengths [μm]:1.0642⇒0.5321 / T[℃]:20 / Δθⁱⁿt[deg]:0.063 / Note:5mol% MgO]76 deg
Angular and temperature bandwidth - Δθⁱⁿt [SHG, o+o ⇒ e / Interaction wavelengths [μm]:1.0642⇒0.5321 / T[℃]:20 / θₚₘ[deg]:76 / Note:5mol% MgO]0.063 deg
Angular and temperature bandwidth - T [SHG, o+o ⇒ e / Interaction wavelengths [μm]:1.0642⇒0.5321 / θₚₘ[deg]:90 / ΔT[℃]:0.68 / Note:0.6mol% MgO]25.4 ℃
Angular and temperature bandwidth - θₚₘ [SHG, o+o ⇒ e / Interaction wavelengths [μm]:1.0642⇒0.5321 / T[℃]:25.4 / ΔT[℃]:0.68 / Note:0.6mol% MgO]90 deg
Angular and temperature bandwidth - ΔT [SHG, o+o ⇒ e / Interaction wavelengths [μm]:1.0642⇒0.5321 / T[℃]:25.4 / θₚₘ[deg]:90 / Note:0.6mol% MgO]0.68 ℃
Angular and temperature bandwidth - T [SHG, o+o ⇒ e / Interaction wavelengths [μm]:1.0642⇒0.5321 / θₚₘ[deg]:90 / Δθⁱⁿt[deg]:2.16 / ΔT[℃]:0.73 / Note:5mol% MgO]107 ℃
Angular and temperature bandwidth - θₚₘ [SHG, o+o ⇒ e / Interaction wavelengths [μm]:1.0642⇒0.5321 / T[℃]:107 / Δθⁱⁿt[deg]:2.16 / ΔT[℃]:0.73 / Note:5mol% MgO]90 deg
Angular and temperature bandwidth - Δθⁱⁿt [SHG, o+o ⇒ e / Interaction wavelengths [μm]:1.0642⇒0.5321 / T[℃]:107 / θₚₘ[deg]:90 / ΔT[℃]:0.73 / Note:5mol% MgO]2.16 deg
Angular and temperature bandwidth - ΔT [SHG, o+o ⇒ e / Interaction wavelengths [μm]:1.0642⇒0.5321 / T[℃]:107 / θₚₘ[deg]:90 / Δθⁱⁿt[deg]:2.16 / Note:5mol% MgO]0.73 ℃
Angular and temperature bandwidth - T [SHG, o+o ⇒ e / Interaction wavelengths [μm]:1.0642⇒0.5321 / θₚₘ[deg]:90 / ΔT[℃]:0.73 / Note:5mol% MgO]110.6 ℃
Angular and temperature bandwidth - θₚₘ [SHG, o+o ⇒ e / Interaction wavelengths [μm]:1.0642⇒0.5321 / T[℃]:110.6 / ΔT[℃]:0.73 / Note:5mol% MgO]90 deg
Angular and temperature bandwidth - ΔT [SHG, o+o ⇒ e / Interaction wavelengths [μm]:1.0642⇒0.5321 / T[℃]:110.6 / θₚₘ[deg]:90 / Note:5mol% MgO]0.73 ℃
Temperature derivative of refractive index of LiNbO3 doped with 5mol%MgO - dnₒ/dT×10⁶ [λ[µm]:0.53975 / dnₑ/dT×10⁶[ K⁻¹]:72.763]16.663 K⁻¹
Temperature derivative of refractive index of LiNbO3 doped with 5mol%MgO - dnₑ/dT×10⁶ [λ[µm]:0.53975 / dnₒ/dT×10⁶[ K⁻¹]:16.663]72.763 K⁻¹
Temperature derivative of refractive index of LiNbO3 doped with 5mol%MgO - dnₒ/dT×10⁶ [λ[µm]:0.6328 / dnₑ/dT×10⁶[ K⁻¹]:64.866]12.121 K⁻¹
Temperature derivative of refractive index of LiNbO3 doped with 5mol%MgO - dnₑ/dT×10⁶ [λ[µm]:0.6328 / dnₒ/dT×10⁶[ K⁻¹]:12.121]64.866 K⁻¹
Temperature derivative of refractive index of LiNbO3 doped with 5mol%MgO - dnₒ/dT×10⁶ [λ[µm]:1.0795 / dnₑ/dT×10⁶[ K⁻¹]:54.19]4.356 K⁻¹
Temperature derivative of refractive index of LiNbO3 doped with 5mol%MgO - dnₑ/dT×10⁶ [λ[µm]:1.0795 / dnₒ/dT×10⁶[ K⁻¹]:4.356]54.19 K⁻¹
Temperature derivative of refractive index of LiNbO3 doped with 5mol%MgO - dnₒ/dT×10⁶ [λ[µm]:1.3414 / dnₑ/dT×10⁶[ K⁻¹]:52.665]5.895 K⁻¹
Temperature derivative of refractive index of LiNbO3 doped with 5mol%MgO - dnₑ/dT×10⁶ [λ[µm]:1.3414 / dnₒ/dT×10⁶[ K⁻¹]:5.895]52.665 K⁻¹
Absolute value of the second-order nonlinear coefficient d₃₁ [5mol%MgO:LiNbO3 / 0.852µm]4.9pm/V
Absolute value of the second-order nonlinear coefficient d₃₃ [5mol%MgO:LiNbO3 / 0.852µm]28.4pm/V
Absolute value of the second-order nonlinear coefficient d₃₁ [5mol%MgO:LiNbO3 / 1.064µm]4.4pm/V
Absolute value of the second-order nonlinear coefficient d₃₃ [5mol%MgO:LiNbO3 / 1.064µm]25.0pm/V
Absolute value of the second-order nonlinear coefficient d₃₁ [5mol%MgO:LiNbO3 / 1.313µm]3.4pm/V
Absolute value of the second-order nonlinear coefficient d₃₃ [5mol%MgO:LiNbO3 / 1.313µm]20.3pm/V
Refractive Index [Magnesium-doped lithium niobate / 25°C / 355nm]2.38482
Refractive Index [Magnesium-doped lithium niobate / 25°C / 406nm]2.31248
Refractive Index [Magnesium-doped lithium niobate / 25°C / 532nm]2.2253
Refractive Index [Magnesium-doped lithium niobate / 25°C / 633nm]2.19323
Refractive Index [Magnesium-doped lithium niobate / 25°C / 1064nm]2.14757
Refractive Index [Magnesium-doped lithium niobate / 50°C / 355nm]2.38778
Refractive Index [Magnesium-doped lithium niobate / 50°C / 406nm]2.31441
Refractive Index [Magnesium-doped lithium niobate / 50°C / 532nm]2.22644
Refractive Index [Magnesium-doped lithium niobate / 50°C / 633nm]2.19424
Refractive Index [Magnesium-doped lithium niobate / 50°C / 1064nm]2.14861
Refractive Index [Magnesium-doped lithium niobate / 75°C / 355nm]2.39152
Refractive Index [Magnesium-doped lithium niobate / 75°C / 406nm]2.31718
Refractive Index [Magnesium-doped lithium niobate / 75°C / 532nm]2.22819
Refractive Index [Magnesium-doped lithium niobate / 75°C / 633nm]2.19567
Refractive Index [Magnesium-doped lithium niobate / 75°C / 1064nm]2.14966

Key Features

High homogeneity; wide transparency range; high damage threshold; good optoelectronic properties; good optoelectronic elasticity; reduced photorefractive effects of the intrinsic material.

Datasheet

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Supplier Information

Cr
Crylink
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Shanghai Crylink Technology Co., Ltd. was jointly established by Shanghai Yangtze Delta Innovation Institute, Baoshan District state-owned platform, and Dr. Yongjun Dong's team. Located in Baoshan High-tech Industrial Park, the company focuses on R&D and production of laser materials and devices. Main products include laser crystals, nonlinear crystals, bonded crystals, and devices, with full-chain capabilities from crystal growth, optical polishing, laser coating to device packaging. Its subsidiary, Nanjing Guangbao Optoelectronics Technology Co., Ltd., operates the 'Meta-laser' and 'Guangbao Optoelectronics' brands. Products are widely used in laser processing, medical aesthetics, LiDAR, optical communications, defense, scientific research, aerospace, and other fields.

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