LiIO₃

LiIO₃

Supplier
Crylink
Category
Optical Crystals
Origin
China

Lithium iodate (LiIO₃) is a negative uniaxial crystal with a relatively high nonlinear optical coefficient, a broad transparency range, and resistance to radiation damage. It can be used in nonlinear, acousto-optic, and piezoelectric applications. It can also be used in 347 nm ruby lasers as a medium for second-harmonic generation and parametric oscillation, and in short-pulse, broadband ultrasonic transducers. Other uses include frequency doubling, third-harmonic generation, and frequency mixing of low- and medium-power lasers.

Specification Snapshot
Crystal Structure
Hexagonal crystal system
Crystal Structure
Negative uniaxial crystal
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Overview

Lithium iodate (LiIO₃) is a negative uniaxial crystal with a relatively high nonlinear optical coefficient, a broad transparency range, and resistance to radiation damage. It can be used in nonlinear, acousto-optic, and piezoelectric applications. It can also be used in 347 nm ruby lasers as a medium for second-harmonic generation and parametric oscillation, and in short-pulse, broadband ultrasonic transducers. Other uses include frequency doubling, third-harmonic generation, and frequency mixing of low- and medium-power lasers.

Specifications

ParameterValue
Transmitted Wavefront Distortion [@633 nm]Better than λ/4 @ 633 nm
Outer Diameter Tolerance(W±0.2mm) x (H±0.2 mm) x (L+0.5 /-0.2mm)
Effective clear aperture> 90% Central region
Flatness [@633 nm]λ/4 @ 633 nm
Surface finish20/10 to MIL-PRF-13830B
Parallelism> 20‘’
Perpendicularity5’
Angle Tolerance<±0.5°
Crystal StructureHexagonal crystal system
Crystal StructureNegative uniaxial crystal
Point group6
Melting point420℃
Density4.487 g/cm³
Mohs hardness3.5–4.0
Transparency range280–4000nm
Absorption coefficient [@1064 nm,]< 0.05cm⁻¹
Refractive Index [@1064 nm]nₒ = 1.8571, nₑ = 1.7165
Refractive Index [@800 nm]nₒ = 1.8676, nₑ = 1.7245
Refractive Index [@532 nm]nₒ = 1.8982, nₑ = 1.7480
Type 1 SHG phase-matching range570–4000nm
Type 1 SHG acceptance [@1064 nm- Angle , mrad×cm]0.77
Type 1 SHG acceptance [@1064 nm-spectrum, cm⁻¹×cm]12.74
Type 1 SHG acceptance [@1064 nm-Type 1 SHG Walk-off angle @1064 nm, mrad]74.3
Type 1 SHG acceptance d₃₁ [@1064 nm-Nonlinear coefficient / @1064 nm)]d₃₁=4.4 pm/V(@1064 nm)
Type 1 SHG acceptance [@1064 nm-effective nonlinearity]deff = d₃₁sinθ
Type 1 SHG acceptance [@1064 nm- Damage Threshold / @1064 nm, 10 ns]> 100MW/cm² @ 1064 nm, 10 ns
Type 1 SHG acceptance [@1064 nm-Sellmeier equation (λ in μm)]nₒ²=3.415716+0.047031/(λ²-0.035306)-0.008801λ²
Type 1 SHG acceptance [@1064 nm-Sellmeier equation (λ in μm)]nₑ²=2.918692+0.035145/(λ²-0.028224)-0.003641λ²

Key Features

High nonlinear optical coefficient; broad transparency range; wide phase-matching range; good temperature stability of the refractive index; low damage threshold; applicable to low- and medium-power lasers.

Datasheet

Product Datasheet
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Supplier Information

Cr
Crylink
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Shanghai Crylink Technology Co., Ltd. was jointly established by Shanghai Yangtze Delta Innovation Institute, Baoshan District state-owned platform, and Dr. Yongjun Dong's team. Located in Baoshan High-tech Industrial Park, the company focuses on R&D and production of laser materials and devices. Main products include laser crystals, nonlinear crystals, bonded crystals, and devices, with full-chain capabilities from crystal growth, optical polishing, laser coating to device packaging. Its subsidiary, Nanjing Guangbao Optoelectronics Technology Co., Ltd., operates the 'Meta-laser' and 'Guangbao Optoelectronics' brands. Products are widely used in laser processing, medical aesthetics, LiDAR, optical communications, defense, scientific research, aerospace, and other fields.

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