KTP Nonlinear crystal

KTP Nonlinear crystal

Supplier
Crylink
Category
Optical Crystals
Origin
China

Potassium titanyl phosphate (KTiOPO₄, KTP) has a high nonlinear coefficient, approximately 15 times that of KDP, and high thermal conductivity, 2 times that of BNN crystals. It has broad temperature and angular phase-matching acceptance ranges, high gray-track resistance and optical damage threshold, no moisture absorption or deliquescence, and no decomposition below 900℃. It also offers good mechanical properties, an easily polished crystal surface, and small mismatch. Its frequency-doubling efficiency at 1064nm can reach approximately 80%. The crystal can be used to make frequency-doubling, frequency-mixing, electro-optic modulation, optical parametric oscillation, and optical waveguide devices.

Specification Snapshot
Crystal Structure
Orthorhombic crystal system, space group Pna2₁, point group mm2
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Overview

Potassium titanyl phosphate (KTiOPO₄, KTP) has a high nonlinear coefficient, approximately 15 times that of KDP, and high thermal conductivity, 2 times that of BNN crystals. It has broad temperature and angular phase-matching acceptance ranges, high gray-track resistance and optical damage threshold, no moisture absorption or deliquescence, and no decomposition below 900℃. It also offers good mechanical properties, an easily polished crystal surface, and small mismatch. Its frequency-doubling efficiency at 1064nm can reach approximately 80%. The crystal can be used to make frequency-doubling, frequency-mixing, electro-optic modulation, optical parametric oscillation, and optical waveguide devices.

Specifications

ParameterValue
Chemical formulaKTiOPO₄
Crystal StructureOrthorhombic crystal system, space group Pna2₁, point group mm2
Lattice parametersa=6.404Å, b=10.616Å, c=12.814Å, Z=8
Melting point1172°C
Mohs hardness5
Density3.01 g/cm³
Thermal conductivity13W/m/K
Coefficient of thermal expansionax=11×10⁻⁶/℃, ay=9×10⁻⁶/℃, az=0.6×10⁻⁶/℃
Damage Threshold [@1064 nm,TEM₀₀, 10ns,10HZ(AR-coated)]>0.5 @1064 nm,TEM₀₀, 10ns,10HZ(AR-coated)
Damage Threshold [@532 nm,TEM₀₀, 10ns,10HZ(AR-coated)]>0.3 @532 nm,TEM₀₀, 10ns,10HZ(AR-coated)
SHG phase-matching range497 ~ 1800nm (Type II)
Nonvanishing nonlinear magnetization coefficientdeff(II)≈(d₂₄- d₁₅)sin2φsin2θ- (d₁₅sin2φ+ d₂₄cos2φ)sinθ
Nonvanishing nonlinear magnetization coefficient d₃₁d₃₁=6.5 pm/V
Nonvanishing nonlinear magnetization coefficient d₂₄d₂₄=7.6 pm/V
Nonvanishing nonlinear magnetization coefficient d₃₂d₃₂= 5 pm/V
Nonvanishing nonlinear magnetization coefficient d₁₅d₁₅=6.1 pm/V
Nonvanishing nonlinear magnetization coefficient d₃₃d₃₃=13.7 pm/V
Thermo-optic coefficient dnₓ/dTdnₓ/dT=1.1*10⁻⁵/℃
Thermo-optic coefficient dn_y/dTdn_y/dT=1.3*10⁻⁵/℃
Thermo-optic coefficient dn_z/dTdn_z/dT=1.6*10⁻⁵/℃
Temperature acceptance [Type II SHG@1064nm for Nd:YAG lasers]24°C·cm
Spectral acceptance [Type II SHG@1064nm for Nd:YAG lasers]0.56nm·cm
Angle Reception [Type II SHG@1064nm for Nd:YAG lasers]14.2mrad·cm (φ); 55.3mrad·cm(θ)
Walk-off angle [Type II SHG@1064nm for Nd:YAG lasers]0.55°
Transmission range350~4500nm
Absorption coefficient [@1064nm / @532nm;@ 1064nm;<1%/cm @ 532nm]<0.1%/cm @ 1064nm;<1%/cm @ 532nm
Refractive Index [@1064nm]nₓ=1.7377, n_y=1.7453, n_z=1.8297 @1064nm
Refractive Index [@532nm]nₓ=1.7780, n_y=1.7886, n_z=1.8887 @532nm
Sellmeier equation (λ in μm)nₓ²=3.0065+0.03901/(λ²-0.04251)-0.01327λ²
Sellmeier equation (λ in μm)n_y²=3.0333+0.04154/(λ²-0.04547)-0.01408λ²
Sellmeier equation (λ in μm)n_z²=3.3134+0.05694/(λ²-0.05658)-0.01682λ²

Key Features

High-temperature resistance; high thermal conductivity; small mismatch; high impedance ratio; broad transmission band; low temperature sensitivity; good mechanical properties; large nonlinear optical coefficient; stable chemical and mechanical properties; high electro-optic coefficient and low dielectric constant.

Datasheet

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Supplier Information

Cr
Crylink
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Shanghai Crylink Technology Co., Ltd. was jointly established by Shanghai Yangtze Delta Innovation Institute, Baoshan District state-owned platform, and Dr. Yongjun Dong's team. Located in Baoshan High-tech Industrial Park, the company focuses on R&D and production of laser materials and devices. Main products include laser crystals, nonlinear crystals, bonded crystals, and devices, with full-chain capabilities from crystal growth, optical polishing, laser coating to device packaging. Its subsidiary, Nanjing Guangbao Optoelectronics Technology Co., Ltd., operates the 'Meta-laser' and 'Guangbao Optoelectronics' brands. Products are widely used in laser processing, medical aesthetics, LiDAR, optical communications, defense, scientific research, aerospace, and other fields.

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