HGTR-KTP Nonlinear crystal

HGTR-KTP Nonlinear crystal

Supplier
Crylink
Category
Optical Crystals
Origin
China

HGTR-KTP (high gray-track-resistant KTP) addresses gray tracking, which appears directly as black or gray damage marks inside the crystal. HGTR-KTP nonlinear crystals substantially reduce Ti⁺³ ion-center defects within the crystal during laser frequency doubling. They offer a large nonlinear optical coefficient, high thermal conductivity, small mismatch and walk-off angle, resistance to deliquescence, and stable chemical and mechanical properties. They are widely used as frequency-doubling crystals for conversion from 1064-532 nm in low- and medium-power Nd:YAG and Nd:YVO₄ lasers. They can also be used to make frequency-doubling, frequency-mixing, electro-optic modulation, optical parametric oscillation, and optical waveguide devices.

Specification Snapshot
Crystal Structure
Orthorhombic crystal system, space group Pna21, point group mm2
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Overview

HGTR-KTP (high gray-track-resistant KTP) addresses gray tracking, which appears directly as black or gray damage marks inside the crystal. HGTR-KTP nonlinear crystals substantially reduce Ti⁺³ ion-center defects within the crystal during laser frequency doubling. They offer a large nonlinear optical coefficient, high thermal conductivity, small mismatch and walk-off angle, resistance to deliquescence, and stable chemical and mechanical properties. They are widely used as frequency-doubling crystals for conversion from 1064-532 nm in low- and medium-power Nd:YAG and Nd:YVO₄ lasers. They can also be used to make frequency-doubling, frequency-mixing, electro-optic modulation, optical parametric oscillation, and optical waveguide devices.

Specifications

ParameterValue
Chemical formulaHGTR-KTiOPO₄
Crystal StructureOrthorhombic crystal system, space group Pna21, point group mm2
Lattice parametersa=6.404Å
Lattice parametersb=10.616Å
Lattice parametersc=12.814Å
Lattice parametersZ=8
Mohs hardness5
Density3.01 g/cm³
Melting point1172°C
Thermal conductivity13 W/m/K
Coefficient of thermal expansionaₓ=11x10⁻⁶/℃
Coefficient of thermal expansiona_y=9x10⁻⁶/℃
Coefficient of thermal expansiona_z=0.6x10⁻⁶/℃
SHG phase-matching range497-1800nm (Type II)
Nonlinear coefficient [@1064nm]deff(II)≈(d₂₄-d₁₅)sin2φsin2θ-(d₁₅sin2φ+d₂₄cos2φ)sinθ
Nonlinear coefficient d₃₁ [@1064nm]d₃₁=2.54pm/V
Nonlinear coefficient d₃₂ [@1064nm]d₃₂=1.35pm/V
Nonlinear coefficient d₃₃ [@1064nm]d₃₃=16.9pm/V
Nonlinear coefficient d₂₄ [@1064nm]d₂₄=3.64pm/V
Nonlinear coefficient d₁₅ [@1064nm]d₁₅=1.91pm/V
Thermo-optic coefficient dnₓ/dTdnₓ/dT=1.1*10⁻⁵/℃
Thermo-optic coefficient dn_y/dTdn_y/dT=1.3*10⁻⁵/℃
Thermo-optic coefficient dn_z/dTdn_z/dT=1.6*10⁻⁵/℃
Damage Threshold [@1064 nm,TEM₀₀, 10ns,10HZ(AR-coated)]>0.5 @1064 nm,TEM₀₀, 10ns,10HZ(AR-coated)
Damage Threshold [@532 nm,TEM₀₀, 10ns,10HZ(AR-coated)]>0.3 @532 nm,TEM₀₀, 10ns,10HZ(AR-coated)
Transparency range350-4500 nm
Absorption coefficient [@1064 nm]<0.1%/cm @1064 nm
Absorption coefficient [@532 nm]<1%/cm @532 nm
Refractive Index [@1064nm]nₓ=1.7377, n_y=1.7453, n_z=1.8297 @1064nm
Refractive Index [@532nm]nₓ=1.7780, n_y=1.7886, n_z=1.8887 @532nm
Sellmeier equation (λ in μm)nₓ²=3.0065+0.03901/(λ²-0.04251)-0.01327λ² n_y²=3.0333+0.04154/(λ²-0.04547)-0.01408λ² n_z²=3.3134+0.05694/(λ²-0.05658)-0.01682λ²

Key Features

Nondeliquescent; high optical quality; low half-wave voltage; large nonlinear coefficient; high resistance to gray tracking; high optical-damage threshold; stable chemical and mechanical properties; broad temperature and angular matching acceptance ranges.

Datasheet

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Supplier Information

Cr
Crylink
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Shanghai Crylink Technology Co., Ltd. was jointly established by Shanghai Yangtze Delta Innovation Institute, Baoshan District state-owned platform, and Dr. Yongjun Dong's team. Located in Baoshan High-tech Industrial Park, the company focuses on R&D and production of laser materials and devices. Main products include laser crystals, nonlinear crystals, bonded crystals, and devices, with full-chain capabilities from crystal growth, optical polishing, laser coating to device packaging. Its subsidiary, Nanjing Guangbao Optoelectronics Technology Co., Ltd., operates the 'Meta-laser' and 'Guangbao Optoelectronics' brands. Products are widely used in laser processing, medical aesthetics, LiDAR, optical communications, defense, scientific research, aerospace, and other fields.

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