BaGa₂GeSe₆

BaGa₂GeSe₆

Supplier
Crylink
Category
Optical Crystals
Origin
China

BaGa₂GeSe₆ (barium gallium germanium selenide), abbreviated BGGSe, is a trigonal crystal in space group R3. It has a high laser damage threshold, a broad transmission range (0.5~18μm), moderate birefringence (0.08~0.11), a large nonlinear coefficient (d₁₁=23.6pm/V), and stable chemical properties. It requires neither cumbersome post-processing such as annealing nor post-growth treatment, has high surface chemical stability and crystal symmetry, and is easy to process. It can be pumped by Nd:YAG lasers and has important potential for infrared laser frequency conversion, including CO and CO₂ laser frequency doubling and mid- and far-infrared generation by optical parametric oscillation. The low dispersion and high damage threshold of BGGSe provide advantages for ultrabroadband frequency mixing and ultrashort-pulse output.

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Overview

BaGa₂GeSe₆ (barium gallium germanium selenide), abbreviated BGGSe, is a trigonal crystal in space group R3. It has a high laser damage threshold, a broad transmission range (0.5~18μm), moderate birefringence (0.08~0.11), a large nonlinear coefficient (d₁₁=23.6pm/V), and stable chemical properties. It requires neither cumbersome post-processing such as annealing nor post-growth treatment, has high surface chemical stability and crystal symmetry, and is easy to process. It can be pumped by Nd:YAG lasers and has important potential for infrared laser frequency conversion, including CO and CO₂ laser frequency doubling and mid- and far-infrared generation by optical parametric oscillation. The low dispersion and high damage threshold of BGGSe provide advantages for ultrabroadband frequency mixing and ultrashort-pulse output.

Specifications

ParameterValue
Crystal systemTrigonal crystal system, space group R3
Nonlinear coefficient d₁₁d₁₁=66pm/V
Damage Threshold110MW/cm²
Unit-cell coefficienta=9.5967(5)Å,b=9.5967(5)Å,c=8.6712(7)Å,α=β=90°,γ=120°,Z=1
Transmission range0.5 -18μm
Birefringence0.08-0.11
Melting point880℃
Orientation accuracy<+-0.1°
Surface finish20/10 per MIL-O-13830A
Surface figure [@632.8nm for T>=1mm]λ/8@632.8nm for T>=1mm
Optical-face tolerance+0/-0.1mm
Length Tolerance±0.1mm
Parallelism30″
Perpendicularity10′
Edge bevel<0.2mm×45°

Key Features

Frequency-doubling coefficient 6 times that of AgGaS₂; insoluble in dilute acids, with good chemical stability; strong nonlinear optical effect; high far-infrared transmittance and large birefringence; high laser-damage threshold; broad transmission range; no need for complex postprocessing such as annealing; high crystal symmetry and easy processing; higher efficiency than ZGP and AgGaSe₂ crystals over 2.5-9μm.

Datasheet

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Supplier Information

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Crylink
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Shanghai Crylink Technology Co., Ltd. was jointly established by Shanghai Yangtze Delta Innovation Institute, Baoshan District state-owned platform, and Dr. Yongjun Dong's team. Located in Baoshan High-tech Industrial Park, the company focuses on R&D and production of laser materials and devices. Main products include laser crystals, nonlinear crystals, bonded crystals, and devices, with full-chain capabilities from crystal growth, optical polishing, laser coating to device packaging. Its subsidiary, Nanjing Guangbao Optoelectronics Technology Co., Ltd., operates the 'Meta-laser' and 'Guangbao Optoelectronics' brands. Products are widely used in laser processing, medical aesthetics, LiDAR, optical communications, defense, scientific research, aerospace, and other fields.

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BaGa₂GeSe₆
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